Mystery of Madonna and Child painting solved

Chemists have solved a 20-year mystery surrounding the date of a Madonna and Child painting, the "de Brecy Tondo," painted by an as-yet unidentified artist. However, a debate continues as to who painted the "de Brecy Tondo," which looks suspiciously similar to the "Sistine Madonna," painted by the renowned Italian Renaissance artist Raphael.

Howell Edwards, a specialist in Raman spectroscopy at the University of Bradford in the United Kingdom, used laser-based technology to detect yellow pigments and glue typical of the Renaissance period, which dates the painting between the 14th and 16th centuries.

His findings suggest that the "de Brecy Tondo" and the "Sistine Madonna" were painted during the same time period.

"Prior to Professor Edwards' work, there has been no consensus amongst art historians as to the age of the painting," said Timothy Benoy, secretary and trustee of the de Brecy Trust, and coauthor of a report on the new finding, published in the February issue of the journal Analytical and Bioanalytical Chemistry.

Edwards found evidence of massicot, a lead-based yellow pigment used by artists prior to the introduction of a new pigment called Naples Yellow in the 1700s. Massicot, also found in Vermeer's 1670 painting "Young Lady Seated at the Virginals," has been used to date previous works of art.

As well, the laser research detected organic residues characteristic of a vegetable- or starch-based glue, typical of the Renaissance period.